cis-Tetrachloridobis(1H-imidazole-κN3)platinum(IV)
نویسندگان
چکیده
منابع مشابه
cis-Tetrachloridobis(1H-imidazole-κN 3)platinum(IV)
In the title complex, cis-[PtCl(4)(C(3)H(4)N(2))(2)], the Pt(IV) ion lies on a twofold rotation axis and is coordinated in a slightly distorted octa-hedral geometry. The dihedral angle between the imidazole rings is 69.9 (2)°. In the crystal, mol-ecules are linked by N-H⋯Cl hydrogen bonds, forming a three-dimensional network.
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In the title compound, [Co(C(8)H(4)O(4))(C(3)H(4)N(2))(3)(H(2)O)(2)]·H(2)O, the cisoid angles are in the range 85.59 (5)-93.56 (5)°, while two equal transoid angles deviate significantly from the ideal linear angle, the third being almost linear. One carboxyl-ate group is almost coplanar [1.23 (13)°] with the plane of its parent aromatic ring, although it has one O-atom donor involved in one co...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2012
ISSN: 1600-5368
DOI: 10.1107/s1600536812013323